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Determine the freezing point of a solution that contains 0.31 mol of sucrose in 175 g of water. Kf = 1.86°C/m


A) 3.3°C
B) 1.1°C
C) 0.0°C
D) -1.1°C
E) -3.3°C

F) A) and B)
G) D) and E)

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Potassium hydrogen phosphate is used in the preparation of nondairy powdered creamers. Calculate the molarity of a solution prepared by dissolving 238 g of K2HPO4 in enough water to produce 275 mL of solution.


A) 0.732 M
B) 0.865 M
C) 2.66 M
D) 4.97 M
E) None of these choices are correct.

F) A) and C)
G) None of the above

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A 0.89% (w/v) sodium chloride solution is referred to as physiological saline solution because it has the same concentration of salts as human blood. What is the molarity of a physiological saline solution?


A) 0.0028 M
B) 0.015 M
C) 0.15 M
D) 0.30 M
E) 0.35 M

F) A) and E)
G) A) and B)

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From the following list of aqueous solutions and water, select the one with the lowest freezing point.


A) 0.75 m (NH4) 3PO4
B) 1.0 m CaSO4
C) 1.0 m LiClO4
D) 1.5 m CH3OH, methyl alcohol
E) pure water

F) A) and D)
G) C) and D)

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Hexachlorophene is used as a disinfectant in germicidal soaps. What mass of hexachlorophene ( Hexachlorophene is used as a disinfectant in germicidal soaps. What mass of hexachlorophene (   = 406.9 g/mol)  must be added to 125 g of chloroform to give a solution with a boiling point of 62.60°C? K<sub>b</sub> = 3.63°C/m, boiling point of pure chloroform = 61.70°C A)  12.6 g B)  17.2 g C)  31.0 g D)  34.4 g E)  101 g = 406.9 g/mol) must be added to 125 g of chloroform to give a solution with a boiling point of 62.60°C? Kb = 3.63°C/m, boiling point of pure chloroform = 61.70°C


A) 12.6 g
B) 17.2 g
C) 31.0 g
D) 34.4 g
E) 101 g

F) B) and C)
G) A) and B)

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A solution of ethanol (C2H6O) in water is sometimes used as a disinfectant. 1.00 L of this solution contains 553 g of ethanol and 335 g of water. What is the mole fraction of ethanol in this solution?


A) 0.377
B) 0.392
C) 0.553
D) 0.608
E) 0.623

F) A) and D)
G) B) and D)

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The backbone of a protein chain consists of carbon, nitrogen, and oxygen atoms.

A) True
B) False

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Barbiturates are synthetic drugs used as sedatives and hypnotics. Barbital ( Barbiturates are synthetic drugs used as sedatives and hypnotics. Barbital (   = 184.2 g/mol)  is one of the simplest of these drugs. What is the boiling point of a solution prepared by dissolving 42.5 g of barbital in 825 g of acetic acid? K<sub>b</sub> = 3.07°C/m; boiling point of pure acetic acid = 117.9°C A)  117.0°C B)  117.7°C C)  118.1°C D)  118.8°C E)  >120°C = 184.2 g/mol) is one of the simplest of these drugs. What is the boiling point of a solution prepared by dissolving 42.5 g of barbital in 825 g of acetic acid? Kb = 3.07°C/m; boiling point of pure acetic acid = 117.9°C


A) 117.0°C
B) 117.7°C
C) 118.1°C
D) 118.8°C
E) >120°C

F) D) and E)
G) None of the above

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What is the molality of a solution prepared by dissolving 86.9 g of diethyl ether, C4H10O, in 425 g of benzene, C6H6?


A) 0.362 m
B) 0.498 m
C) 2.01 m
D) 2.76 m
E) None of these choices are correct.

F) A) and B)
G) D) and E)

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Carbon tetrachloride, once widely used in fire extinguishers and as a dry cleaning fluid, has been found to cause liver damage to those exposed to its vapors over long periods of time. What is the boiling point of a solution prepared by dissolving 375 g of sulfur (S8, Carbon tetrachloride, once widely used in fire extinguishers and as a dry cleaning fluid, has been found to cause liver damage to those exposed to its vapors over long periods of time. What is the boiling point of a solution prepared by dissolving 375 g of sulfur (S8,   = 256.5 g/mol)  in 1250 g of CCl<sub>4</sub>? Kb = 5.05°C/m, boiling point of pure CCl<sub>4</sub> = 76.7°C? A)  70.8°C B)  75.2°C C)  78.2°C D)  82.6°C E)  >85°C = 256.5 g/mol) in 1250 g of CCl4? Kb = 5.05°C/m, boiling point of pure CCl4 = 76.7°C?


A) 70.8°C
B) 75.2°C
C) 78.2°C
D) 82.6°C
E) >85°C

F) All of the above
G) None of the above

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Under physiological conditions, amino acids in solution carry


A) no electrical charges.
B) a net positive charge, due to an -NH3+ group or groups.
C) a net negative charge, due to a -COO- group or groups.
D) both -NH2 and -COOH groups.
E) both -NH3+ and -COO- groups.

F) A) and B)
G) None of the above

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Which of the following aqueous solutions will have the lowest osmotic pressure?


A) 0.10 m KOH
B) 0.10 m RbCl
C) 0.05 m CaSO4
D) 0.05 m BaCl2
E) 0.10 m K2SO4

F) A) and C)
G) None of the above

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Calculate the freezing point of a solution made by dissolving 3.50 g of potassium chloride ( Calculate the freezing point of a solution made by dissolving 3.50 g of potassium chloride (   = 74.55 g/mol)  in 100.0 g of water. Assume ideal behavior for the solution; K<sub>f</sub> = 1.86°C/m. A)  -1.7°C B)  -0.9°C C)  0.0°C D)  0.9°C E)  1.7°C = 74.55 g/mol) in 100.0 g of water. Assume ideal behavior for the solution; Kf = 1.86°C/m.


A) -1.7°C
B) -0.9°C
C) 0.0°C
D) 0.9°C
E) 1.7°C

F) A) and E)
G) None of the above

Correct Answer

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Which of the following pairs of ions is arranged so that the ion with the smaller charge density is listed first?


A) K+, Rb+
B) Cl-, K+
C) Cl-, Br-
D) Ca2+, Ba2+
E) None of these choices are correct.

F) All of the above
G) C) and D)

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The larger the ion, the greater in magnitude will be its heat of hydration.

A) True
B) False

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The solubility of the oxidizing agent potassium permanganate is 7.1 g per 100.0 g of water at 25°C. What is the mole fraction of potassium permanganate in this solution?


A) 0.0080
B) 0.0086
C) 0.066
D) 0.45
E) 0.48

F) A) and B)
G) None of the above

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How many moles of solute particles are present in 100.0 mL of 2.50 M (NH4) 3PO4?


A) 0.100 mol
B) 0.250 mol
C) 0.500 mol
D) 0.750 mol
E) 1.00 mol

F) C) and E)
G) All of the above

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A 0.100 m MgSO4 solution has a freezing point of -0.23°C. What is the van't Hoff factor for this solution? Kf = 1.86°C/m


A) 0.62
B) 1.0
C) 1.2
D) 2.0
E) 4.0

F) A) and E)
G) A) and D)

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Calcium nitrite is used as a corrosion inhibitor in lubricants. What is the molality of a solution prepared by dissolving 18.5 g of calcium nitrite in 83.5 g of distilled water?


A) 0.0342 m
B) 0.0855 m
C) 0.222 m
D) 0.444 m
E) 1.68 m

F) A) and D)
G) All of the above

Correct Answer

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All solutions are mixtures.

A) True
B) False

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