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Consider the following adjectives used to describe types of spectrum: continuous, line, atomic, emission, absorption How many of them are appropriate to describe the spectrum of radiation absorbed by a sample of mercury vapor?


A) one
B) two
C) three
D) four
E) five

F) B) and E)
G) A) and C)

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In an atom, the square of an electron's wave function


A) becomes zero at the nucleus.
B) is smallest near the nucleus.
C) is largest near the nucleus.
D) may be zero at more than one point.
E) tends to infinity at large distances from the nucleus.

F) B) and C)
G) A) and E)

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An infrared wave has a wavelength of 6.5 * 10¯4 cm. What is this distance in angstroms, Å?


A) 6.5 *10¯4 Å
B) 2.2 * 10¯4 Å
C) 4.6 *103 Å
D) 6.5 * 104 Å
E) 6.5 * 106 Å

F) A) and B)
G) A) and E)

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Electromagnetic radiation can be specified by its wavelength ( λ\lambda ) , its frequency ( ν\nu ) or its period ( Electromagnetic radiation can be specified by its wavelength ( \lambda ) , its frequency ( \nu )  or its period ( ) . The period  is the time it takes one complete wavelength to pass a point in space. Based on this information, what is the mathematical relationship between  \nu  and  ? A)  ( \nu  = 1/ )  B)  ( \nu =  )  C)  (  =  \nu /c)  D)  (c =   * \nu )  E)  (  = c/ \nu )  ) . The period 11ef222e_4621_1d73_8db4_2113957fc093_TB7799_11is the time it takes one complete wavelength to pass a point in space. Based on this information, what is the mathematical relationship between ν\nu and 11ef222e_4621_1d73_8db4_2113957fc093_TB7799_11?


A) ( ν\nu = 1/11ef222e_4621_1d73_8db4_2113957fc093_TB7799_11)
B) ( ν\nu = 11ef222e_4621_1d73_8db4_2113957fc093_TB7799_11)
C) (11ef222e_4621_1d73_8db4_2113957fc093_TB7799_11 = ν\nu /c)
D) (c = 11ef222e_4621_1d73_8db4_2113957fc093_TB7799_11 * ν\nu )
E) (11ef222e_4621_1d73_8db4_2113957fc093_TB7799_11 = c/ ν\nu )

F) A) and C)
G) A) and B)

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Which of the following frequencies of electromagnetic radiation has the shortest wavelength?


A) 1 kilohertz
B) 1 terahertz
C) 1 dekahertz
D) 1 gigahertz
E) 1 megahertz

F) A) and C)
G) None of the above

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In the Rydberg equation, for a fixed value of n1, the longest wavelength line has n2 = \infty .

A) True
B) False

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Which of the following is a correct set of quantum numbers for an electron in a 5f orbital?


A) n = 5, l = 3, ml = +1
B) n = 5, l = 2, ml = +3
C) n = 4, l = 3, ml = 0
D) n = 4, l = 2, ml = +1
E) n = 5, l = 4, ml = 3

F) A) and E)
G) B) and C)

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In not more than three lines for each answer, briefly outline one important scientific contribution of each of the following: A) Planck B) de Broglie C) Heisenberg

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A) Planck is responsible for first propo...

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Select the arrangement of electromagnetic radiation which starts with the lowest energy and increases to greatest energy.


A) radio, visible, infrared, ultraviolet
B) infrared, visible, ultraviolet, microwave
C) visible, ultraviolet, infrared, gamma rays
D) X-radiation, visible, infrared, microwave
E) microwave, infrared, visible, ultraviolet

F) A) and D)
G) A) and C)

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The orientation in space of an atomic orbital is associated with


A) the principal quantum number (n) .
B) the angular momentum quantum number (l) .
C) the magnetic quantum number (ml) .
D) the spin quantum number (ms) .
E) None of these choices is correct.

F) A) and B)
G) A) and C)

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The interference pattern seen when light passes through narrow, closely spaced slits, is due to


A) diffraction.
B) reflection.
C) refraction.
D) dispersion.
E) deflection.

F) A) and C)
G) A) and B)

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Who developed an empirical equation from which the wavelengths of lines in the spectrum of hydrogen atoms can be calculated?


A) Planck
B) de Broglie
C) Bohr
D) Rutherford
E) Rydberg

F) B) and C)
G) A) and D)

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The Rydberg equation is an example of an empirical equation.

A) True
B) False

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Continuous spectra are characteristic of molecules in the gas phase.

A) True
B) False

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Which of the following is a correct set of quantum numbers for an electron in a 3d orbital?


A) n = 3, l = 0, ml = -1
B) n = 3, l = 1, ml = +3
C) n = 3, l = 2, ml = 3
D) n = 3, l = 3, ml = +2
E) n = 3, l = 2, ml = -2

F) B) and D)
G) B) and C)

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In the quantum mechanical treatment of the hydrogen atom, the probability of finding an electron at any point is proportional to the wave function Ψ \varPsi .

A) True
B) False

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Consider the following adjectives used to describe types of spectrum: continuous, line, atomic, emission, absorption How many of them are appropriate to describe the spectrum of radiation given off by a black body?


A) none
B) one
C) two
D) three
E) four

F) C) and E)
G) B) and C)

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A sprinter must average 24.0 mi/h to win a 100-m dash in 9.30 s. What is his wavelength at this speed if his mass is 84.5 kg?


A) 7.29* 10¯37 m
B) 3.26 * 10¯37 m
C) 5.08 *10¯30 m
D) 1.34 * 10¯30 m
E) None of these choices is correct.

F) All of the above
G) C) and E)

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A photon has an energy of 5.53 * 10¯17 J. What is its frequency in s¯1?


A) 3.66 * 10¯501
B) 1.20 * 10¯171
C) 3.59 * 10¯91
D) 2.78 * 1081
E) 8.35 * 10161

F) C) and D)
G) A) and C)

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According to the Heisenberg uncertainty principle, if the uncertainty in the speed of an electron is 3.5 *103 m/s, the uncertainty in its position (in m) is at least:


A) 1.7 * 10¯8 m
B) 6.6 * 10¯8 m
C) 17 m
D) 66 m
E) None of these choices is correct.

F) A) and B)
G) B) and C)

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