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A gas cylinder containing 1.50 mol compressed methane has a volume of 3.30 L. What pressure does the methane exert on the walls of the cylinder if its temperature is 25°C? (R = 0.08206 L • atm/K • mol)


A) 9.00 × 10-2 atm
B) 0.933 atm
C) 1.11 atm
D) 1.70 atm
E) 11.1 atm

F) B) and D)
G) C) and D)

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If a fixed amount of a gas is at a pressure of 2.71 atm and has a volume of 85.3 L at a temperature of 173.4 K, what is the final temperature of the gas if the pressure changes to 1.04 atm in a 105.3 L container?


A) 49.8 K
B) 75.9 K
C) 366.0 K
D) 82.1 K
E) 557.8 K

F) B) and D)
G) A) and B)

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A sample of nitrogen gas has the temperature drop from 250.°C to 150.°C at constant pressure. What is the final volume if the initial volume is 310. mL?


A) 0.186 L
B) 0.251 L
C) 0.383 L
D) 0.410 L
E) 0.517 L

F) A) and E)
G) All of the above

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"The volume of an ideal gas is directly proportional to the number of moles of the gas at constant temperature and pressure" is a statement of ________ law.


A) Charles's
B) Boyle's
C) Dalton's
D) Avogadro's
E) Gay-Lussac's

F) A) and C)
G) C) and D)

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A pressure that will support a column of Hg to a height of 256 mm would support a column of water to what height? The density of mercury is 13.6 g/cm3; the density of water is 1.00 g/cm3.


A) 348 cm
B) 1.00 × 102 ft
C) 18.8 mm
D) 33.8 ft
E) 76.0 cm

F) A) and E)
G) B) and D)

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What is the temperature in Celsius at 77 K, which is the normal boiling point of liquid nitrogen?


A) -350°C
B) -196°C
C) 350°C
D) 196°C
E) 3.55°C

F) A) and C)
G) B) and C)

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What is the density of carbon dioxide gas at -25.2°C and 98.0 kPa? (R = 0.08206 L • atm/K • mol, 1 atm = 101,325 Pa)


A) 0.232 g/L
B) 0.279 g/L
C) 0.994 g/L
D) 1.74 g/L
E) 2.09 g/L

F) A) and B)
G) B) and D)

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Calculate the volume of H2(g) at 273 K and 2.00 atm that will be formed when 275 mL of 0.725 M HCl solution reacts with 50.0 g Zn(s) to give hydrogen gas and aqueous zinc chloride. (R = 0.08206 L • atm/K • mol)


A) 0.56 L
B) 1.12 L
C) 2.23 L
D) 4.47 L
E) 3.54 L

F) C) and E)
G) A) and E)

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When a closed-ended manometer is used for pressure measurements, and the closed end is under vacuum, the level of manometer liquid in the closed arm can never be lower than that in the other arm.

A) True
B) False

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What volume of CO2 gas at 645 torr and 800. K could be produced by the decomposition of 45.0 g of CaCO3? CaCO3(s) → CaO(s) + CO2(g) (R = 0.08206 L • atm/K • mol)


A) 0.449 L
B) 22.4 L
C) 25.0 L
D) 34.8 L
E) 45.7 mL

F) D) and E)
G) C) and E)

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Which represents the definition of pressure?


A) volume/density
B) temperature × area
C) moles/volume
D) force/area
E) volume × force

F) A) and E)
G) D) and E)

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For a substance that remains a gas under all of the conditions listed, deviation from the ideal gas law would be most pronounced at


A) 100°C and 2.0 atm.
B) 0°C and 2.0 atm.
C) -100°C and 2.0 atm.
D) -100°C and 4.0 atm.
E) 100°C and 4.0 atm.

F) A) and D)
G) All of the above

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A sample of an ideal gas has its volume doubled while its temperature remains constant. If the original pressure was 100 torr, what is the new pressure?


A) 10 torr
B) 50 torr
C) 100 torr
D) 200 torr
E) 1000 torr

F) A) and C)
G) C) and D)

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A 1.325 g sample of an unknown vapor occupies 368 mL at 114°C and 946 mm Hg. The empirical formula of the compound is NO2. What is the molecular formula of the compound?


A) NO2
B) N4O8
C) N3O6
D) N2O4
E) N5O10

F) D) and E)
G) A) and B)

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A sample of propane, a component of LP gas, has a volume of 35.3 L at 315 K and 922 torr. What is its volume at STP? (R = 0.08206 L • atm/K • mol, 1 atm = 760 torr)


A) 25.2 L
B) 30.6 L
C) 33.6 L
D) 37.1 L
E) 49.2 L

F) A) and B)
G) A) and C)

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What volume of chlorine gas at 25°C and 0.950 atm can be produced by the reaction of 12.0 g of MnO2 in excess HCl(aq) ? MnO2(s) + 4HCl(aq) → MnCl2(aq) + 2H2O(l) + Cl2(g) (R = 0.08206 L • atm/K • mol)


A) 5.36 × 10-3 L
B) 0.138 L
C) 0.282 L
D) 3.09 L
E) 3.55 L

F) A) and B)
G) None of the above

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Give five examples of elements that occur as gases at room temperature and pressure.

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(Answers will vary.)...

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________ ________ is the pressure exerted by the Earth's atmosphere.

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Atmospheri...

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A sample of a gas has an initial pressure of 0.987 atm and a volume of 12.8 L. What is the final pressure if the volume is increased to 25.6 L?


A) 2.03 atm
B) 1.97 atm
C) 0.494 atm
D) 0.003 atm
E) 323.4 atm

F) D) and E)
G) A) and D)

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Select the gas with the largest root-mean-square molecular speed at 25°C.


A) NH3
B) CO
C) H2
D) SF6
E) All the gases have the same root-mean-square molecular speed at 25°C.

F) A) and B)
G) None of the above

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