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According to Molecular Orbital Theory, two separate 1s orbitals interact to form what molecular orbital(s)


A) ( σ\sigma ) only
B) ( σ\sigma ) and σ\sigma *
C) ( π\pi ) only
D) ( π\pi ) and π\pi *
E) ( σ\sigma ) and π\pi

F) B) and E)
G) All of the above

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There are no π\pi -bonds in C2H6.

A) True
B) False

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Give the number of lone pairs around the central atom and the geometry of the ion NO2-.


A) 0 lone pairs, linear
B) 1 lone pair, bent
C) 2 lone pair, bent
D) 3 lone pairs, bent
E) 3 lone pairs, linear

F) A) and E)
G) B) and D)

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A sp2 hybridized terminal oxygen atom (bonded to one other atom only) with 2 lone pairs of electrons has what type of bonding


A) 1 π\pi and 1 σ\sigma bonds
B) 2 π\pi and 1 σ\sigma bonds
C) 1 π\pi and 2 σ\sigma bonds
D) 0 π\pi and 2 σ\sigma bonds
E) 0 π\pi and 3 σ\sigma bonds

F) C) and D)
G) B) and D)

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The number of pi bonds in the molecule below is The number of pi bonds in the molecule below is   A)  2 B)  4 C)  6 D)  10 E)  15


A) 2
B) 4
C) 6
D) 10
E) 15

F) C) and D)
G) A) and D)

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Indicate the type of hybrid orbitals used by the central atom in CCl4.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and B)
G) A) and C)

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The geometry of the ClF3 molecule is best described as:


A) distorted tetrahedron
B) trigonal planar
C) tetrahedral
D) T-shaped
E) trigonal pyramidal

F) A) and E)
G) A) and D)

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Shown here is the correct Lewis structure for PF5. According to VSEPR theory how many electrons are bonded to the P atom Shown here is the correct Lewis structure for PF<sub>5</sub>. According to VSEPR theory how many electrons are bonded to the P atom   A)  Four B)  Eight C)  Ten D)  Twelve E)  None of the above


A) Four
B) Eight
C) Ten
D) Twelve
E) None of the above

F) B) and D)
G) A) and B)

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Consider the species N2-, N2, and N2+. Which of these species will be paramagnetic


A) N2 and N2-
B) N2+ and N2
C) N2+ and N2-
D) only N2-
E) none are paramagnetic

F) D) and E)
G) B) and C)

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Indicate the type of hybrid orbitals used by the central atom in TeF4.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) All of the above
G) A) and C)

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The bond angles in SF5+ are expected to be


A) 90 \circ .
B) 120 \circ .
C) 90 \circ and 120 \circ .
D) 90 \circ and 180 \circ .
E) 90 \circ , 120 \circ , and 180 \circ .

F) A) and B)
G) C) and D)

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Two py orbitals from two different atoms can interact to form a pi bonding molecular orbital.

A) True
B) False

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A sp hybridized terminal nitrogen atom (bonded to one other atom only) with 1 lone pair of electrons has what type of bonding


A) 1 π\pi and 2 σ\sigma bonds
B) 2 π\pi and 1 σ\sigma bonds
C) 2 π\pi and 2 σ\sigma bonds
D) 0 π\pi and 2 σ\sigma bonds
E) 0 π\pi and 3 σ\sigma bonds

F) C) and E)
G) C) and D)

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The bond angles in CO32- are expected to be


A) a little less than 109.5 \circ .
B) 109.5 \circ .
C) a little less than 120 \circ .
D) 120 \circ .
E) a little more than 120 \circ .

F) A) and D)
G) B) and E)

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The geometrical structure of PF5 and IF5 are both square pyramidal.

A) True
B) False

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Which of the following correctly lists species in order of increasing bond order


A) C2 < Li2 < Be2 < N2
B) Be2 < Li2 < C2 < N2
C) N2 < Be2 < Li2 < C2
D) N2 < C2 < Li2 < Be2
E) Be2 < C2 < N2 < Li2

F) B) and D)
G) C) and E)

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Valence Bond Theory alone can be used to determine that O2 is paramagnetic.

A) True
B) False

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There are two π\pi -bonds in C2H4.

A) True
B) False

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There is one π\pi -bond in N2H2.

A) True
B) False

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Which one of the following molecules has a non-zero dipole moment


A) BeCl2
B) Br2
C) BF3
D) IBr
E) CO2

F) C) and D)
G) C) and E)

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