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What is the freezing point of a solution prepared from 50.0 g ethylene glycol (C2H6O2) and 85.0 g H2O? Kf of water is 1.86°C/m.


A) 17.6°C
B) 1.50°C
C) -1.50°C
D) -17.6°C
E) -176°C

F) A) and B)
G) B) and E)

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Calculate the molality of 6.0 M H2SO4 solution.The density of the solution is 1.34 g/mL.


A) 4.48 m
B) 7.98 m
C) 8.10 m
D) 8.43 m
E) 10.2 m

F) B) and E)
G) C) and D)

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Plasma is the fluid portion of blood.The concentration of acetylsalicylic acid (aspirin, C9H8O4, molar mass = 180.g/mol)in your plasma is found to be 2.99 × 10-4 M after you take two tablets of aspirin.If the volume of your plasma is 5.85 L, what is the molality, m, of aspirin in your blood? (Assume density of plasma is 1.00 g/mL.)

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An aqueous dextrose solution having a density of 1.04 g/cm3 freezes at -1.15°C.Find the osmotic pressure of this solution at 25°C.Kf of water is 1.86 °C/m; molecular mass of dextrose = 180.16 g/mol.


A) 12.9 atm
B) 13.8 atm
C) 14.1 atm
D) 15.1 atm
E) 120 atm

F) B) and E)
G) B) and D)

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A 23.0% by mass LiCl solution is prepared in water.What is the mole fraction of the water?


A) 0.113
B) 0.127
C) 0.873
D) 0.887
E) 0.911

F) A) and D)
G) A) and C)

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During osmosis


A) pure solvent diffuses through a membrane but solutes do not.
B) pure solutes diffuse through a membrane but solvent does not.
C) pure solvent and a solution both diffuse at the same time through a membrane.
D) gases diffuse through a membrane into a solution and build up pressure.

E) A) and D)
F) A) and C)

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Using your knowledge of osmosis or osmotic pressure explain the following statement: When sprinkled with sugar, a dish of sliced fruit will form its own juice.

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The water inside the fruit cel...

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What is the boiling point of a solution of 12.0 g of urea (CH4N2O) in 165.0 g of water? (Kb (H2O) = 0.52 °C/m)


A) 99.4°C
B) 100.0 °C
C) 100.6°C
D) 106.2°C
E) 108.4°C

F) A) and B)
G) A) and C)

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According to Raoult's law, which statement is false?


A) The vapor pressure of a solvent over a solution decreases as its mole fraction increases.
B) The solubility of a gas increases as the temperature decreases.
C) The vapor pressure of a solvent over a solution is less than that of pure solvent.
D) The greater the pressure of a gas over a solution the greater its solubility.
E) Ionic solutes dissociate in solution causing an enhancement of all colligative properties.

F) A) and E)
G) A) and B)

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The solubility of a solid always increases with increasing solvent temperature.

A) True
B) False

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A 20.0 % by mass solution of phosphoric acid (H3PO4) in water has a density of 1.114 g/mL at 20°C.What is the molarity of this solution?


A) 0.0114 M
B) 0.0568 M
C) 0.114 M
D) 2.27 M
E) 11.4 M

F) A) and B)
G) A) and C)

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Which of the following aqueous solutions has the largest molality of benzoic acid (C6H5COOH) ?


A) 3.5 m C6H5COOH
B) mole fraction, X = 0.050 C6H5COOH
C) 2.50 mass % C6H5COOH
D) 3.2 g C6H5COOH in 650.g of H2O
E) 1.5 moles C6H5COOH in 65.0 moles of H2O

F) C) and D)
G) A) and D)

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Which of the following solutions has the largest molality of HCl?


A) 4.5 m HCl
B) mole fraction, X = 0.110 HCl
C) 15.0 mass % HCl
D) 10.5 g HCl in 750 g of H2O
E) 3.6 moles HCl in 45.0 moles of H2O

F) C) and E)
G) B) and D)

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Using your knowledge of osmosis or osmotic pressure explain the following statement: In trees and plants water is drawn from the soil up into the branches and leaves.

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The water passes into the cell...

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What is the mole fraction of sodium phosphate in a 0.142 M Na3PO4(aq)solution that has a density of 1.015 g/mL?

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How many grams of water are needed to dissolve 27.8 g of ammonium nitrate NH4NO3 in order to prepare a 0.452 m solution?


A) 769 g
B) 36.2 g
C) 100.g
D) 0.157 g
E) 157 g

F) A) and B)
G) A) and C)

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Arrange the following aqueous solutions in order of increasing boiling points: 0.050m Mg(NO3) 2; 0.100m ethanol; 0.090m NaCl.


A) Mg(NO3) 2 < NaCl < ethanol
B) ethanol < Mg(NO3) 2 < NaCl
C) ethanol < NaCl < Mg(NO3) 2
D) NaCl < ethanol < Mg(NO3) 2
E) Mg(NO3) 2 < ethanol < NaCl

F) B) and E)
G) B) and D)

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Which of the following gives the molarity of a 17.0% by mass solution of sodium acetate, CH3COONa (molar mass = 82.0 g/mol) in water? The density of the solution is 1.09 g/mL.


A) 2.26 × 10-6 M
B) 0.207 M
C) 2.07 M
D) 2.26 M
E) 2.72 M

F) All of the above
G) D) and E)

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To interconvert the concentration units of molarity (M)and mass percent, you must also know the density of the solution.

A) True
B) False

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The solubility of nitrogen gas at 25°C and a nitrogen pressure of 522 mmHg is 4.7 × 10-4 mol/L.What is the value of the Henry's Law constant in mol/L·atm?


A) 9.0 × 10-7 mol/L·atm
B) 3.2 × 10-4 mol/L·atm
C) 4.7 × 10-4 mol/L·atm
D) 6.8 × 10-4 mol/L·atm
E) 1.5 × 103 mol/L·atm

F) D) and E)
G) A) and E)

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