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Samples of the following volatile liquids are opened simultaneously at one end of a room. If you are standing at the opposite end of this room, which species would you smell first? (Assume that your nose is equally sensitive to all these species.)


A) ethyl acetate (CH3COOC2H5)
B) camphor (C10H16O)
C) diethyl ether (C2H5OC2H5)
D) naphthalene (C10H8)
E) pentanethiol (C5H11SH)

F) A) and B)
G) C) and E)

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Calculate the number of moles of gas contained in a 10.0 L tank at 22°C and 105 atm.(R = 0.08206 L.atm/K.mol)


A) 1.71 * 10-3 mol
B) 0.0231 mol
C) 1.03 mol
D) 43.4 mol
E) 582 mol

F) A) and E)
G) C) and D)

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A sample of hydrogen gas was collected over water at 21°C and 685 mmHg. The volume of the container was 7.80 L. Calculate the mass of H2(g) collected. (Vapor pressure of water = 18.6 mmHg at 21°C.)


A) 0.283 g
B) 0.572 g
C) 0.589 g
D) 7.14 g
E) 435 g

F) A) and B)
G) A) and C)

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How many molecules of N2 gas can be present in a 2.5 L flask at 50°C and 650 mmHg?


A) 2.1 * 10-23 molecules
B) 4.9 * 1022 molecules
C) 3.1 * 1023 molecules
D) 3.6 * 1025 molecules
E) 0.081 molecules

F) A) and D)
G) B) and C)

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At constant pressure, the density of a gas depends on temperature.Does the density increase or decrease as the temperature increases?

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Determine the pressure of the gas trapped in the apparatus shown below when the atmospheric pressure is 695 mmHg. Determine the pressure of the gas trapped in the apparatus shown below when the atmospheric pressure is 695 mmHg.   A) 45 mmHg B) 650 mmHg C) 695 mmHg D) 740 mmHg E) 760 mmHg


A) 45 mmHg
B) 650 mmHg
C) 695 mmHg
D) 740 mmHg
E) 760 mmHg

F) B) and E)
G) A) and D)

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The mole fraction of oxygen molecules in dry air is 0.2095. What volume of dry air at 1.00 atm and 25°C is required for burning 1.00 L of hexane (C6H14, density = 0.660 g/mL) completely, yielding carbon dioxide and water?


A) 187 L
B) 712 L
C) 1780 L
D) 894 L
E) 8490

F) B) and D)
G) B) and E)

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What is the pressure of the sample of gas trapped in the open-tube mercury manometer shown below if atmospheric pressure is 742 mmHg and h = 16.7 cm? What is the pressure of the sample of gas trapped in the open-tube mercury manometer shown below if atmospheric pressure is 742 mmHg and h = 16.7 cm?

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A 0.271 g sample of an unknown vapor occupies 294 mL at 140°C and 847 mmHg.The empirical formula of the compound is CH2. What is the molecular formula of the compound?


A) CH2
B) C2H4
C) C3H6
D) C4H8
E) C6H12

F) A) and D)
G) B) and E)

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A spacecraft is filled with 0.500 atm of O2 and 0.500 atm of He. If there is a very small hole in the side of this craft such that gas is lost slowly into outer space,


A) He is lost 2.8 times faster than O2 is lost.
B) He is lost 8 times faster than O2 is lost.
C) He is lost twice as fast as O2 is lost.
D) O2 is lost 2.8 times faster than He is lost.
E) O2 is lost 8 times faster than He is lost.

F) All of the above
G) C) and E)

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Calculate the density, in g/L, of chlorine (Cl2) gas at STP.


A) 2.13 * 10-2 g/L
B) 46.9 g/L
C) 1.58 g/L
D) 3.16 g/L
E) 0.316 kg/L

F) All of the above
G) A) and E)

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Ammonium nitrite undergoes decomposition to produce only gases as shown below. NH4NO2(s) \rarr N2(g)+ 2H2O(g) How many liters of gas will be produced by the decomposition of 32.0 g of NH4NO2 at 525°C and 1.5 atm?

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What is the pressure of the sample of gas trapped in the open-tube mercury manometer shown below if atmospheric pressure is 736 mmHg and h = 9.2 cm? What is the pressure of the sample of gas trapped in the open-tube mercury manometer shown below if atmospheric pressure is 736 mmHg and h = 9.2 cm?   A) 92 mmHg B) 644 mmHg C) 736 mmHg D) 828 mmHg


A) 92 mmHg
B) 644 mmHg
C) 736 mmHg
D) 828 mmHg

E) B) and D)
F) B) and C)

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Determine the molar mass of Freon-11 gas if a sample weighing 0.597 g occupies 100.cm3 at 95°C, and 1,000.mmHg.


A) 0.19 g/mol
B) 35.3 g/mol
C) 70.9 g/mol
D) 137 g/mol
E) 384 g/mol

F) D) and E)
G) B) and C)

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At what temperature will a fixed mass of gas with a volume of 125 L at 15°C and 750 mmHg occupy a volume of 101 L at a pressure of 645 mm Hg?


A) -73°C
B) 10.4°C
C) 2°C
D) 34°C
E) 200°C

F) B) and C)
G) None of the above

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What will happen to the height (h) of the mercury column in the manometer shown below if the stopcock is opened, given that the atmospheric pressure is 755 mmHg? What will happen to the height (h) of the mercury column in the manometer shown below if the stopcock is opened, given that the atmospheric pressure is 755 mmHg?   A) h will decrease B) h will not change C) h will increase D) not enough information given to answer the question


A) h will decrease
B) h will not change
C) h will increase
D) not enough information given to answer the question

E) A) and D)
F) All of the above

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Gases are sold in large cylinders for laboratory use. What pressure, in atmospheres, will be exerted by 2,500 g of oxygen gas (O2) when stored at 22°C in a 40.0 L cylinder?


A) 3.55 atm
B) 1,510 atm
C) 47.3 atm
D) 7.56 * 104 atm
E) 10.2 atm

F) A) and C)
G) A) and D)

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A particular coal sample contains 2.32% S.When the coal is burned, the sulfur is converted to sulfur dioxide gas. What volume of SO2(g), measured at 25°C and 749 mmHg, is produced by burning 2.0 * 106 lb of this coal? (1 lb = 454 g)

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1.6 * 10

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The gas pressure in an aerosol can is 1.8 atm at 25°C. If the gas is an ideal gas, what pressure would develop in the can if it were heated to 475°C?


A) 0.095 atm
B) 0.717 atm
C) 3.26 atm
D) 4.52 atm
E) 34.2 atm

F) A) and B)
G) C) and D)

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The pressure of a gas sample was measured to be 489 mmHg.Which of the following is not an equivalent statement of that pressure? (1 atm = 1.01325 * 105 Pa)


A) 65.2 kPa
B) 6.52 * 104 Pa
C) 489 torr
D) 0.811 atm

E) B) and C)
F) A) and B)

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