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Which of the following is a correct set of quantum numbers for an electron in a 3d orbital?


A) n = 3, l = 0, ml = -1
B) n = 3, l = 1, ml = +3
C) n = 3, l = 2, ml = 3
D) n = 3, l = 3, ml = +2
E) n = 3, l = 2, ml = -2

F) A) and B)
G) B) and D)

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The orientation in space of an atomic orbital is associated with


A) the principal quantum number (n) .
B) the angular momentum quantum number (l) .
C) the magnetic quantum number (ml) .
D) the spin quantum number (ms) .
E) none of the above.

F) All of the above
G) C) and E)

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According to the Rydberg equation, the longest wavelength (in nm) in the series of H-atom lines with n1 = 3 is


A) 1875 nm.
B) 1458 nm.
C) 820. nm.
D) 656 nm.
E) 365 nm.

F) C) and D)
G) A) and E)

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A wave function for an electron is called an atomic orbital.

A) True
B) False

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Which scientist first proposed that the electron in the hydrogen atom can have only certain energies?


A) Planck
B) Einstein
C) Bohr
D) Rydberg
E) Heisenberg

F) All of the above
G) C) and E)

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What type of spectrum, if any, would be produced if the light radiated by a heated atomic gas were to be dispersed through a prism?


A) a continuous band of color
B) a continuous band of color with some dark lines (missing wavelengths)
C) only blue light
D) only red light
E) discrete lines of different colors

F) A) and E)
G) A) and D)

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Which of the following frequencies of electromagnetic radiation has the shortest wavelength?


A) 1 kilohertz
B) 1 terahertz
C) 1 dekahertz
D) 1 gigahertz
E) 1 megahertz

F) A) and B)
G) None of the above

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In not more than three lines for each answer, briefly outline one important scientific contribution of each of the following: a. Planck b. de Broglie c. Heisenberg

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a. Planck is responsible for first propo...

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Use the Rydberg equation to calculate the wavelength, in nm, of the least energetic (longest wavelength) line in the visible series (n1 = 2) of the spectrum of atomic hydrogen.

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Continuous spectra are characteristic of molecules in the gas phase.

A) True
B) False

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Contact lenses can focus light due to the ____________ of the waves.


A) diffraction
B) reflection
C) refraction
D) dispersion
E) interference

F) C) and D)
G) A) and B)

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According to the Heisenberg uncertainty principle, if the uncertainty in the speed of an electron is 3.5 × 103 m/s, the uncertainty in its position (in m) is at least


A) 1.7 × 10-8 m.
B) 6.6 × 10-8 m.
C) 17 m.
D) 66 m.
E) none of the above.

F) A) and B)
G) A) and C)

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The energy of a photon is directly proportional to the wavelength of the radiation.

A) True
B) False

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Excited hydrogen atoms radiate energy in the


A) infrared region only.
B) visible region only.
C) ultraviolet region only.
D) visible and ultraviolet regions only.
E) infrared, visible, and ultraviolet regions.

F) All of the above
G) B) and E)

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Line spectra are characteristic of atoms in the gas phase.

A) True
B) False

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Select the arrangement of electromagnetic radiation which starts with the lowest energy and increases to greatest energy.


A) radio, infrared, ultraviolet, gamma rays
B) radio, ultraviolet, infrared, gamma rays
C) gamma rays, infrared, radio, ultraviolet
D) gamma rays, ultraviolet, infrared, radio
E) infrared, ultraviolet, radio, gamma rays

F) B) and C)
G) A) and D)

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An infrared wave has a wavelength of 6.5 × 10-4 cm. What is this distance in angstroms, Å?


A) 6.5 × 10-4 Å
B) 2.2 × 10-4 Å
C) 4.6 × 103 Å
D) 6.5 × 104 Å
E) 6.5 × 106 Å

F) None of the above
G) B) and C)

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According to the Bohr theory of the hydrogen atom, the minimum energy (in J) needed to ionize a hydrogen atom from the n = 2 state is


A) 2.18 × 10-18 J.
B) 1.64 × 10-18 J.
C) 5.45 × 10-19 J.
D) 3.03 × 10-19 J.
E) none of the above.

F) C) and D)
G) B) and E)

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In the Rydberg equation, for a fixed value of n1, the longest wavelength line has n2 = .

A) True
B) False

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Other factors being constant, a heavy object will have a longer de Broglie wavelength than a light object.

A) True
B) False

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