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Manganese dioxide (MnO2) for use in dry cells is made by electrolyzing solutions of Mn2+, where the following reaction occurs at the anode: Mn2+(aq) + 2H2O(l) MnO2(s) + 4H+(aq) + 2e- Using a current of 100. amperes (A), how many hours will it take to produce 5.00 kg of MnO2, according to the above reaction?

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Calculate E°cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous. Calculate E°<sub>cell</sub><sub> </sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.     Overall reaction: 4Al(s)  + 3O<sub>2</sub>(g)  + 12H<sup>+</sup>(aq)  <font face= symbol ></font> 4Al<sup>3+</sup>(aq)  + 6H<sub>2</sub>O(l)  A)  E°<sub>cell</sub> = -2.891 V, nonspontaneous B)  E°<sub>cell</sub> = -2.891 V, spontaneous C)  E°<sub>cell</sub> = 2.891 V, nonspontaneous D)  E°<sub>cell</sub> = 2.891 V, spontaneous E)  Spontaneous, but none of the above values of E°<sub>cell</sub> is correct. Overall reaction: 4Al(s) + 3O2(g) + 12H+(aq) 4Al3+(aq) + 6H2O(l)


A) E°cell = -2.891 V, nonspontaneous
B) E°cell = -2.891 V, spontaneous
C) E°cell = 2.891 V, nonspontaneous
D) E°cell = 2.891 V, spontaneous
E) Spontaneous, but none of the above values of E°cell is correct.

F) C) and E)
G) D) and E)

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A salt bridge provides a path for electrons to move between the anode and cathode compartments of a voltaic cell.

A) True
B) False

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How many grams of oxygen gas will be produced in the electrolysis of water, for every gram of hydrogen gas formed? Reaction: 2H2O(l) 2H2(g) + O2(g)


A) 31.7 g
B) 15.9 g
C) 7.94 g
D) 3.97 g
E) 1.98 g

F) B) and E)
G) D) and E)

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What product forms at the anode during the electrolysis of molten NaBr?


A) Na+(l)
B) Na(l)
C) Br-(l)
D) Br3-(l)
E) Br2(g)

F) C) and E)
G) B) and D)

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A voltaic cell consists of a Hg/Hg22+ electrode (E° = 0.85 V) and a Sn/Sn2+ electrode (E° = -0.14 V) . Calculate [Sn2+] if [Hg22+] = 0.24 M and Ecell = 1.04 V at 25°C.


A) 0.0001 M
B) 0.0007 M
C) 0.005 M
D) 0.03 M
E) 0.05 M

F) C) and D)
G) C) and E)

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A voltaic cell prepared using zinc and iodine has the following cell notation. Zn(s) | Zn2+(aq) || I-(aq) | I2(s) | C(graphite) Which of the following equations correctly represents the balanced, spontaneous, cell reaction?


A) 2I-(aq) + Zn2+(aq) I2(s) + Zn(s)
B) I2(s) + Zn(s) 2I-(aq) + Zn2+(aq)
C) 2I-(aq) + Zn(s) I2(s) + Zn2+(aq)
D) I2(s) + Zn2+(aq) 2I-(aq) + Zn(s)
E) None of the above, since graphite must be in the equation.

F) C) and D)
G) A) and B)

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A galvanic cell is constructed using the two hypothetical half-reactions A galvanic cell is constructed using the two hypothetical half-reactions   a. Write down the balanced equation representing the cell reaction. b. Calculate the standard potential of this cell, E°<sub>cell</sub>. c. Calculate <font face= symbol ></font>G° for the cell reaction. a. Write down the balanced equation representing the cell reaction. b. Calculate the standard potential of this cell, E°cell. c. Calculate G° for the cell reaction.

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a. 2A + D F...

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Examine the following half-reactions and select the strongest oxidizing agent among the substances. Examine the following half-reactions and select the strongest oxidizing agent among the substances.   A)  [PtCl<sub>4</sub>]<sup>2-</sup>(aq)  B)  RuO<sub>4</sub>(s)  C)  HFeO<sub>4</sub><sup>-</sup> (aq)  D)  H<sub>4</sub>XeO<sub>6</sub>(aq)  E)  Cl<sup>-</sup>(aq)


A) [PtCl4]2-(aq)
B) RuO4(s)
C) HFeO4- (aq)
D) H4XeO6(aq)
E) Cl-(aq)

F) A) and C)
G) A) and D)

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What mass of copper will be deposited when 18.2 A are passed through a CuSO4 solution for 45.0 minutes?


A) 16.2 g
B) 33.4 g
C) 40.6 g
D) 81.3 g
E) 163 g

F) A) and B)
G) A) and C)

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A voltaic cell consists of a Ag/Ag+ electrode (E° = 0.80 V) and a Fe2+/Fe3+ electrode (E° = 0.77 V) with the following initial molar concentrations: [Fe2+] = 0.30 M; [Fe3+] = 0.10 M; [Ag+] = 0.30 M. What is the equilibrium concentration of Fe3+? (Assume the anode and cathode solutions are of equal volume, and a temperature of 25°C.)


A) 0.030 M
B) 0.043 M
C) 0.085 M
D) 0.11 M
E) 0.17 M

F) B) and E)
G) D) and E)

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Consider the reaction of iodine with manganese dioxide Consider the reaction of iodine with manganese dioxide   The equilibrium constant for the overall reaction is 8.30 × 10<sup>-7</sup>. Calculate E°<sub>cell</sub> for the reaction at 25°C. A)  -0.36 V B)  -0.18 V C)  -0.12 V D)  -0.060 V E)  none of the above The equilibrium constant for the overall reaction is 8.30 × 10-7. Calculate E°cell for the reaction at 25°C.


A) -0.36 V
B) -0.18 V
C) -0.12 V
D) -0.060 V
E) none of the above

F) A) and B)
G) C) and D)

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Which of the following conditions is most likely to apply to a fully-charged secondary cell?


A) Ecell = E°cell
B) E°cell = 0
C) Q = 1
D) Q < K
E) Q = K

F) A) and B)
G) B) and D)

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A current of 1000. A flows for exactly 1 hour, through a cell in which the following reaction occurs at one of the electrodes. Mg2+ + 2e- Mg a. Calculate the charge, in coulombs, which passes through the circuit in this time. b. Calculate the theoretical mass of Mg (magnesium metal) which is produced in this time.

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a. 3.60 × ...

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Calculate the potential of a voltaic cell (E°cell) if it is required to do 5.43 × 10-3 kJ of work when a charge of 2.50 C is transferred.


A) 2.17 × 103 V
B) 2.17 × 10-3 V
C) 2.17 V
D) 13.6 V
E) 1.36 × 10-2 V

F) D) and E)
G) A) and B)

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What is the E°cell for the cell represented by the combination of the following half-reactions? ClO4-(aq) + 8H+(aq) + 8e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq)  + 8H<sup>+</sup>(aq)  + 8e<sup>-</sup>   Cl<sup>-</sup>(aq)  + 4H<sub>2</sub>O(l)  E°<sup> </sup>= 1.389 V VO<sub>2</sub><sup>+</sup>(aq)  + 2H<sup>+</sup>(aq)  + e<sup>-</sup>   VO<sup>+</sup>(aq)  + H<sub>2</sub>O(l)  E°<sup> </sup>= 0.991 V A)  -0.398 V B)  -2.380 V C)  0.398 V D)  2.380 V E)  none of the above Cl-(aq) + 4H2O(l) E° = 1.389 V VO2+(aq) + 2H+(aq) + e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq)  + 8H<sup>+</sup>(aq)  + 8e<sup>-</sup>   Cl<sup>-</sup>(aq)  + 4H<sub>2</sub>O(l)  E°<sup> </sup>= 1.389 V VO<sub>2</sub><sup>+</sup>(aq)  + 2H<sup>+</sup>(aq)  + e<sup>-</sup>   VO<sup>+</sup>(aq)  + H<sub>2</sub>O(l)  E°<sup> </sup>= 0.991 V A)  -0.398 V B)  -2.380 V C)  0.398 V D)  2.380 V E)  none of the above VO+(aq) + H2O(l) E° = 0.991 V


A) -0.398 V
B) -2.380 V
C) 0.398 V
D) 2.380 V
E) none of the above

F) C) and E)
G) B) and D)

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The line notation, Al(s) | Al3+(aq) || Co2+(aq) | Co(s) , indicates that


A) Co is the reducing agent.
B) Co2+ ions are oxidized.
C) Al is the reducing agent.
D) Al3+ is the reducing agent.
E) aluminum metal is the cathode.

F) All of the above
G) A) and D)

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What is the value of the equilibrium constant for the cell reaction below at 25°C? E°cell = 0.30 V Sn2+(aq) + Fe(s) What is the value of the equilibrium constant for the cell reaction below at 25°C? E°<sub>cell</sub> = 0.30 V Sn<sup>2+</sup>(aq)  + Fe(s)    Sn(s)  + Fe<sup>2+</sup>(aq)  A)  1.2 × 10<sup>5</sup> B)  1.4 × 10<sup>10</sup> C)  8.6 × 10<sup>-6</sup> D)  7.1 × 10<sup>-11</sup> E)  2.3 × 10<sup>23</sup> Sn(s) + Fe2+(aq)


A) 1.2 × 105
B) 1.4 × 1010
C) 8.6 × 10-6
D) 7.1 × 10-11
E) 2.3 × 1023

F) A) and B)
G) None of the above

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Electrons are produced at the cathode of a voltaic cell.

A) True
B) False

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A voltaic cell is prepared using copper and silver. Its cell notation is shown below. Cu(s) | Cu2+(aq) || Ag+(aq) | Ag(s) Which of the following processes occurs at the cathode?


A) Cu(s) Cu2+(aq) + 2e-
B) Cu2+(aq) + 2e- Cu(s)
C) Ag(s) Ag+(aq) + e-
D) Ag+(aq) + e- Ag(s)
E) Cu(s) + 2Ag+(aq) Cu2+(aq) + 2Ag(s)

F) B) and E)
G) A) and C)

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